Why emitted photons have specific wavelengths




















Connect and share knowledge within a single location that is structured and easy to search. As we already know that the electron emits light photons when it travels from one orbit to another, and that causes this transition is the electron absorption of the incoming photon. But when the electron absorbs a photon, it moves to a farther orbit.

Does the outgoing photon have a wavelength similar to the wavelength of the incoming photon? Let me note first that a free electron can never absorb, nor emit a photon due to the restrictions imposed by the energy and the momentum conservation. It can however scatter a photon, which is referred to as Compton scattering. Atoms and solids absorb and emit photons, which often happens due to the transitions of electrons between energy levels although other scenarios are possible - e.

This is why the atomic spectra are composed of discrete lines - they correspond to transitions between different pairs of discrete levels. Simple light scattering, known as Rayleight scattering , does not require a second energy level - it is a second-order "virtual" process. This is why it can happen at any frequency. It is also worth pointing out the combination of the two: the Raman scattering where the photon energy is split into two smaller parts - one is absorbed and the other is emitted as a smaller energy photon or in the reverse order.

Absorption occurs when electrons absorb photons which causes them to gain energy and jump to higher energy levels. Notice emission in the picture above. It shows the electron moving down energy levels. The color of the light emitted would result from the amount of energy as it moves through shells. Absorption is shown by the energy levels increasing as the photon gains energy.

The wavelengths shown relate to the amount of energy in the photon. Notice how the emitted light wavelengths are shorter than the absorbed light wavelengths. This would indicate that the emitted light has more energy in the photon than the absorbed light.

This is important because it shows the shells that electrons move to when light is absorbed or emitted. The energy difference between orbitals can be calculated by measuring the frequency of radiation. Absorption and emission of light can reveal a lot about the structure of an atom. Absorbed light is light that isn't seen while emitted light is light that is seen. When looking at a spectrum of light from a star, how can we tell that the light has undergone What is redshift and blueshift?

What is the redshift of the CMB surface? What is the redshift of the Andromeda galaxy? How do scientists know that there is redshift from a star going away and EM waves have changed lengths? How does redshift differ from blueshift?

See all questions in Light and Fundamental Forces. Kirchoff and Bunsen carefully measured the number and position of all the spectral lines they saw given off by a whole range of materials. These were called emission spectra , and when they had collected enough of them it was clear that each substance produced a very characteristic line spectrum that was unique.

No two substances produced exactly the same series of lines, and if two different materials were combined they collectively gave off all the lines produced by both substances. This, thought Kirchoff and Bunsen, would be a good way of identifying substances in mixtures or in materials that needed to be analyzed.

So they did. In they found a spectrum of lines that they had never seen before, and which did not correspond to any known substance, so, quite rightly, they deduced that they had found a new element, which they called cesium from the Latin word meaning "sky blue". Guess in what part of the spectrum they found the lines! All the research on atomic structure and the hideously difficult-to-understand properties of electrons come together in the topic of "electron energy".

An atom such as lithium has three electrons in various orbitals surrounding the atomic center. These electrons can be bombarded with energy and if they absorb enough of the quanta of energy being transferred they jump about and in the most extreme case, leave the lithium atom completely.

This is called ionization. Partly this difference in the amount of energy needed to dislodge different electrons away from the lithium atomic center is due to the fact that the center of the lithium atom is carrying the positive charges of three protons. Moving a negatively charged electron away from a positively charged atomic center needs more and more energy as the amount of un-neutralized charge increases, thus;. However, the amount of energy needed to remove the first electron is a good measure of what it takes to stimulate an electron to leave its atom, and how tightly it is held there in the first place.

Within the atom, as Bohr pointed out, there are different possible positions for electrons to be found as defined by the principal quantum number , usually written as " n ". Bohr defined the energy of electrons located at these different locations of quantum state by the formula:.

This is usually presented in the form of a diagram see left. If the quantum is too small the electron could not reach the next level, so it doesn't try.



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